根據公式K=S/G，電極常數K可以通過測量電導電極在一定濃度的KCL溶液中的電導G來求得，此時KCL溶液的電導率S是已知的。
由于測量溶液的濃度和溫度不同，以及測量儀器的精度和頻率也不同，電導電極常數K有時會出現較大的誤差，使用一段時間后，電極常數也可能會有變化，因此，新購的電導電極，以及使用一段時間后的電導電極，電極常數應重新測量標定，
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