這一值則被稱為電極常數。在電極間存在均勻電場的情況下，電極常數可以通過幾何尺寸算出。當兩個面積為1cm2的方形極板，之間相隔1cm組成電極時，此電極的常數Q=1cm-1。如果用此對電極測得電導值G=1000μs，則被測溶液的電導率K=1000μs/ cm。
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